Police in Berlin say 123 officers were injured in clashes with leftist protesters over the redevelopment of a district in the east of the city.
About 3,500 protesters marched through Friedrichshain on Saturday. Some were masked and threw missiles, police said.
The protest was the most violent in the past five years, they said.
Tensions have risen since moves began in June to evict squatters in the area. Friedrichshain has undergone rapid gentrification in recent years.
About 1,800 police were deployed at the protest, which began peacefully but escalated into violence. Eighty-six people were arrested, police said.